An in-triphenylaminophane

Org Lett. 2012 Jul 6;14(13):3427-9. doi: 10.1021/ol3014073. Epub 2012 Jun 8.

Abstract

The synthesis and characterization of the triphenylamine-capped cyclophane 3 are described. It proved to be a conformationally rigid molecular propeller, with an inwardly pyramidalized, unreactive amine.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Aniline Compounds / chemistry*
  • Crystallography, X-Ray
  • Ethers, Cyclic / chemical synthesis*
  • Ethers, Cyclic / chemistry
  • Models, Molecular
  • Molecular Structure
  • Piperidines / chemical synthesis*
  • Piperidines / chemistry

Substances

  • Aniline Compounds
  • Ethers, Cyclic
  • Piperidines
  • cyclophane 3