Biosupramolecular nanowires from chlorophyll dyes with exceptional charge-transport properties

Angew Chem Int Ed Engl. 2012 Jun 25;51(26):6378-82. doi: 10.1002/anie.201201961. Epub 2012 May 29.

Abstract

Conductive tubes: Self-assembled nanotubes of a bacteriochlorophyll derivative are reminiscent of natural chlorosomal light-harvesting assemblies. After deposition on a substrate that consists of a non-conductive silicon oxide surface (see picture, brown) and contacting the chlorin nanowires to a conductive polymer (yellow), they show exceptional charge-transport properties.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Chlorophyll / chemistry*
  • Coloring Agents / chemistry*
  • Cryoelectron Microscopy
  • Ions / chemistry
  • Microscopy, Atomic Force
  • Microscopy, Electron, Transmission
  • Models, Molecular
  • Molecular Structure
  • Nanowires / chemistry*
  • Nanowires / ultrastructure

Substances

  • Coloring Agents
  • Ions
  • Chlorophyll