Electric-field-dependent photoconductivity in CdS nanowires and nanobelts: exciton ionization, Franz-Keldysh, and Stark effects

Nano Lett. 2012 Jun 13;12(6):2993-9. doi: 10.1021/nl300749z. Epub 2012 Jun 1.

Abstract

We report on the electric-field-dependent photoconductivity (PC) near the band-edge region of individual CdS nanowires and nanobelts. The quasi-periodic oscillations above the band edge in nanowires and nanobelts have been attributed to a Franz-Keldesh effect. The exciton peaks in PC spectra of the nanowires and thinner nanobelts show pronounced red-shifting due to the Stark effect as the electric field increases, while the exciton ionization is mainly facilitated by strong electron-longitudinal optical (LO) phonon coupling. However, the band-edge transition of thick nanobelts blue-shifts due to the field-enhanced exciton ionization, suggesting partial exciton ionization as the electron-LO phonon coupling is suppressed in the thicker belts. Large Stark shifts, up to 48 meV in the nanowire and 12 meV in the thinner nanobelts, have been achieved with a moderate electric field on the order of kV/cm, indicating a strong size and dimensionality implication due to confinement and surface depletion.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Cadmium Compounds / chemistry*
  • Cadmium Compounds / radiation effects*
  • Electric Conductivity
  • Electromagnetic Fields
  • Ions
  • Light
  • Materials Testing
  • Nanostructures / chemistry*
  • Nanostructures / radiation effects*
  • Selenium Compounds / chemistry*
  • Selenium Compounds / radiation effects*

Substances

  • Cadmium Compounds
  • Ions
  • Selenium Compounds
  • cadmium selenide