Synthesis of YBa2Cu3O(7-δ) and Y2BaCuO5 nanocrystalline powders for YBCO superconductors using carbon nanotube templates

ACS Nano. 2012 Jun 26;6(6):5395-403. doi: 10.1021/nn301262t. Epub 2012 Jun 15.

Abstract

We fabricate nanosized superconducting YBa(2)Cu(3)O(7-δ) (Y-123) and nonsuperconducting Y(2)BaCuO(5) (Y-211) powders using carbon nanotubes as template. The mean particle size of Y-123 and Y-211 is 12 and 30 nm, respectively. The superconducting transition temperature of the Y-123 nanopowder is 90.9 K, similar to that of commercial, micrometer-scale powders fabricated by conventional processing. The elimination of carbon and the formation of a high purity superconducting phase both on the micro- and macroscale is confirmed by Raman spectroscopy and X-ray diffraction. We also demonstrate improvement in the superconducting properties of YBCO single grain bulk samples fabricated using the nanosize Y-211 powder, both in terms of trapped field and critical current density. The former reaches 553 mT at 77 K, with a ∼20% improvement compared to samples fabricated from commercial powders. Thus, our processing method is an effective source of pinning centers in single grain superconductors.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Ceramics / chemistry*
  • Electric Conductivity
  • Macromolecular Substances / chemistry
  • Materials Testing
  • Molecular Conformation
  • Molecular Imprinting / methods*
  • Nanoparticles / chemistry*
  • Nanoparticles / ultrastructure*
  • Particle Size
  • Powders
  • Surface Properties

Substances

  • Macromolecular Substances
  • Powders