Abstract
An efficient and flexible route for the synthesis of α-tertiary (α,α-dibranched) α-silylamines via sequential reactions of sulfonylimidates using readily available phenyldimethylsilyllithium and Grignard reagents is described. The procedure allows successive formation of C-Si/C-C bonds in a single flask.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Amines / chemical synthesis*
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Amines / chemistry
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Catalysis
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Indicators and Reagents
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Lithium / chemistry
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Molecular Structure
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Organometallic Compounds / chemistry*
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Organosilicon Compounds / chemical synthesis*
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Organosilicon Compounds / chemistry
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Stereoisomerism
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Sulfones / chemistry*
Substances
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Amines
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Indicators and Reagents
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Organometallic Compounds
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Organosilicon Compounds
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Sulfones
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phenyldimethylsilyllithium
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Lithium