N-Acetyl-N-[2,4-dicyano-1-(4-meth-oxy-phen-yl)-9,10-dihydro-phenanthren-3-yl]acetamide

Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):o1177-8. doi: 10.1107/S160053681201210X. Epub 2012 Mar 24.

Abstract

In the title compound, C(27)H(21)N(3)O(3), the cyclo-hexa-1,3-diene ring has a screw-boat conformation, and the fused ring system is folded, the dihedral angle between the outer benzene rings being 27.61 (6)°. The N-acetyl-acetamide residue (r.m.s. deviation = 0.0935 Å) has an anti conformation and is essentially perpendicular to the benzene ring to which it is connected [dihedral angle = 89.14 (6)°]; the meth-oxy-benzene group is also twisted out of this ring [dihedral angle = 59.47 (7)°]. The three-dimensional architecture is consolidated by C-H⋯O and C-H⋯π inter-actions.