N'-(3-Bromo-5-chloro-2-hy-droxy-benzyl-idene)-2H-1,3-benzodioxole-5-carbo-hydrazide

Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):o1336-7. doi: 10.1107/S160053681201433X. Epub 2012 Apr 6.

Abstract

The asymmetric unit of the title hydrazone compound, C(15)H(10)BrClN(2)O(4), contains two independent mol-ecules. The dihedral angles between the benzene rings are 38.7 (3)° in one mol-ecule and 24.3 (3)° in the other. Both mol-ecules exist in trans conformations with respect to the C=N double bonds of the central methyl-idene units. Intra-molecular O-H⋯N contacts are observed in both mol-ecules, forming S(6) rings. In the crystal, mol-ecules are linked through N-H⋯O hydrogen bonds into chains along the a axis.