[(4-Methyl-benz-yl)bis-(pyridin-2-ylmeth-yl)amine-κ(3)N,N',N'']bis-(thio-cyanato-κS)copper(II) dichloro-methane hemisolvate

Yan Qi; Yang Li; Zheng-Ping Ma; Qiu-Yun Chen

doi:10.1107/S1600536812011476

[(4-Methyl-benz-yl)bis-(pyridin-2-ylmeth-yl)amine-κ(3)N,N',N'']bis-(thio-cyanato-κS)copper(II) dichloro-methane hemisolvate

Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):m468. doi: 10.1107/S1600536812011476. Epub 2012 Mar 24.

Authors

Yan Qi¹, Yang Li, Zheng-Ping Ma, Qiu-Yun Chen

Affiliation

¹ School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, People's Republic of China.

Abstract

The title compound, [Cu(NCS)(2)(C(20)H(21)N(3))]·0.5CH(2)Cl(2), crystallized with two independent complex mol-ecules (A and B) in the asymmetric unit, accompanied by one dichloro-methane solvent mol-ecule. Each Cu(II) atom has a square-pyramidal geometry, being coordinated by five N atoms, three from the (4-methyl-benz-yl)bis-(pyridin-2-ylmeth-yl)amine ligand and two from the thio-cyanate ligands. In the crystal, the B mol-ecules are linked via C-H⋯S inter-actions, forming chains propagating along [100].