Quantum cascade laser-based photoacoustic sensor for trace detection of formaldehyde gas

Sensors (Basel). 2009;9(4):2697-705. doi: 10.3390/s90402697. Epub 2009 Apr 16.

Abstract

We report on the development of a photoacoustic sensor for the detection of formaldehyde (CH(2)O) using a thermoelectrically cooled distributed-feedback quantum cascade laser operating in pulsed mode at 5.6 μm. A resonant photoacoustic cell, equipped with four electret microphones, is excited in its first longitudinal mode at 1,380 Hz. The absorption line at 1,778.9 cm(-1) is selected for CH(2)O detection. A detection limit of 150 parts per billion in volume in nitrogen is achieved using a 10 seconds time constant and 4 mW laser power. Measurements in ambient air will require water vapour filters.

Keywords: Formaldehyde; Photoacoustic spectroscopy; Quantum cascade laser; Trace gas sensor.