Synthesis of stable monoporphyrinate lanthanide(III) complexes without ancillary ligands

Chem Commun (Camb). 2012 Jun 7;48(45):5611-3. doi: 10.1039/c2cc31015e. Epub 2012 May 1.

Abstract

A new type of porphyrin ligand bearing four triazole groups at the ortho-positions of phenyl rings in tetraphenylporphyrin was synthesized for the formation of monoporphyrinate lanthanide complexes without ancillary ligands.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Coordination Complexes / chemical synthesis*
  • Coordination Complexes / chemistry
  • Lanthanoid Series Elements / chemical synthesis*
  • Lanthanoid Series Elements / chemistry
  • Ligands
  • Metalloporphyrins / chemical synthesis*
  • Metalloporphyrins / chemistry
  • Spectrometry, Fluorescence
  • Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization
  • Triazoles / chemical synthesis
  • Triazoles / chemistry

Substances

  • Coordination Complexes
  • Lanthanoid Series Elements
  • Ligands
  • Metalloporphyrins
  • Triazoles