NTCDA-TTF first axial fusion: emergent panchromatic, NIR optical, multi-state redox and high optical contrast photooxidation

Chem Commun (Camb). 2012 Jul 4;48(52):6475-7. doi: 10.1039/c2cc31274c. Epub 2012 Apr 26.

Abstract

The first synthetic entry into axially fused NTCDA/PMDA-TTF multipolar molecules demonstrates a high optical contrast photooxidation, panchromism, low HOMO-LUMO gap, generation of a stable radical cation, NIR absorption/emission beyond 2150/800 nm and theoretically calculated NLO activity.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Anhydrides / chemistry*
  • Benzoates / chemistry*
  • Cyclopentanes / chemistry*
  • Magnetic Resonance Spectroscopy
  • Naphthalenes / chemistry*
  • Oxidation-Reduction
  • Spectrophotometry, Ultraviolet
  • Spectroscopy, Near-Infrared
  • Stereoisomerism

Substances

  • Anhydrides
  • Benzoates
  • Cyclopentanes
  • Naphthalenes
  • fulvene
  • pyromellitic dianhydride
  • naphthalenetetracarboxylic dianhydride