Highly selective reduction of nitroarenes by iron(0) nanoparticles in water

Chem Commun (Camb). 2012 Aug 18;48(64):7982-4. doi: 10.1039/c2cc30999h. Epub 2012 Apr 24.

Abstract

Highly selective reduction of nitroarenes has been achieved using iron metal nanoparticles in water at room temperature. A wide spectrum of reducible functionalities remained inert under the reaction conditions. During the reaction a change in shape of Fe nanoparticles was observed.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Hydrocarbons, Aromatic / chemistry*
  • Iron / chemistry*
  • Metal Nanoparticles / chemistry*
  • Molecular Structure
  • Nitro Compounds / chemistry*
  • Oxidation-Reduction
  • Particle Size
  • Stereoisomerism
  • Surface Properties
  • Temperature
  • Water / chemistry*

Substances

  • Hydrocarbons, Aromatic
  • Nitro Compounds
  • Water
  • Iron