[W(bipy)(CN)6]-: a suitable metalloligand in the design of heterotrimetallic complexes. The first Cu(II)Ln(III)W(V) trinuclear complexes

Maria-Gabriela Alexandru; Diana Visinescu; Augustin M Madalan; Francesc Lloret; Miguel Julve; Marius Andruh

doi:10.1021/ic300544m

[W(bipy)(CN)6]-: a suitable metalloligand in the design of heterotrimetallic complexes. The first Cu(II)Ln(III)W(V) trinuclear complexes

Inorg Chem. 2012 May 7;51(9):4906-8. doi: 10.1021/ic300544m. Epub 2012 Apr 20.

Authors

Maria-Gabriela Alexandru¹, Diana Visinescu, Augustin M Madalan, Francesc Lloret, Miguel Julve, Marius Andruh

Affiliation

¹ Inorganic Chemistry Laboratory, Faculty of Chemistry, University of Bucharest, Str. Dumbrava Rosie 23, 020464 Bucharest, Romania.

PMID: 22515601
DOI: 10.1021/ic300544m

Abstract

The first 3d-4f-5d heterotrimetallic complexes using [W(V)(bipy)(CN)(6)](-) as a metalloligand were synthesized (bipy = 2,2'-bipyridine). The structural and magnetic properties of three [Cu(II)Ln(III)W(V)] complexes (Ln = Gd, Ho, Tb) are discussed.