Abstract
Pentavalent uranium complexes of the formula U(V)X(2)[N(SiMe(3))(2)](3) (X = F(-), Cl(-), Br(-), N(3)(-), NCS(-)) are accessible from the oxidation of U(III)[N(SiMe(3))(2)](3) through two sequential, one-electron oxidation reactions (halides) and substitution through salt metathesis (pseudohalides). Uranium(v) mixed-halides are also synthesized by successive one-electron oxidation reactions.
Publication types
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Coordination Complexes / chemical synthesis
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Coordination Complexes / chemistry*
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Halogens / chemical synthesis
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Halogens / chemistry*
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Models, Molecular
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Oxidation-Reduction
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Silicon Compounds / chemical synthesis
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Silicon Compounds / chemistry
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Uranium / chemistry*
Substances
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Coordination Complexes
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Halogens
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Silicon Compounds
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Uranium