Electrochemical synthesis of adiponitrile from the renewable raw material glutamic acid

ChemSusChem. 2012 Apr;5(4):617-20. doi: 10.1002/cssc.201100776. Epub 2012 Mar 22.

Abstract

Current affairs: Adiponitrile, used to produce nylon 6.6, is prepared from the renewable compound glutamic acid by an electrochemical route, involving electro-oxidative decarboxylation and Kolbe coupling reactions. The new route is an example of the use of glutamic acid as a versatile substrate in the transformation of biomass into chemicals. Also, it highlights the use of electrochemical methods in biomass conversion.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Chemistry Techniques, Synthetic / methods*
  • Electrochemistry
  • Glutamic Acid / chemistry*
  • Nitriles / chemical synthesis*
  • Nitriles / chemistry*

Substances

  • Nitriles
  • Glutamic Acid
  • adiponitrile