Neutral copper-phosphido-borane complexes: synthesis, characterization, and use as precatalysts in C(sp)-P bond formation

Chem Commun (Camb). 2012 Apr 28;48(34):4088-90. doi: 10.1039/c2cc30723e. Epub 2012 Mar 20.

Abstract

Copper-phosphido-borane complexes were synthesized and isolated for the first time. Their structures were experimentally and computationally investigated. They were shown to display catalytic activity in C(sp)-P bond formation.