2-Chloro-N-(3-methyl-phen-yl)benzamide

Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):o723. doi: 10.1107/S1600536812005739. Epub 2012 Feb 17.

Abstract

In the structure of the title compound, C(14)H(12)ClNO, the ortho-Cl atom in the benzoyl ring is positioned syn to the C=O bond, while the meta-methyl group in the aniline ring is positioned anti to the N-H bond. The amide group forms dihedral angles of 60.1 (1) and 22.0 (1)°, respectively, with the benzoyl and aniline rings, while the angle between these rings is 38.7 (1)°. The crystal structure is stabilized by N-H⋯O hydrogen bonds, which give rise to infinite chains running along the c axis.