7'-(2,5-Dimeth-oxy-phen-yl)-1',3',5',6',7',7a'-hexa-hydro-dispiro-[indan-2,5'-pyrrolo-[1,2-c][1,3]thia-zole-6',2''-indan]-1,3,1''-trione

Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):o560-1. doi: 10.1107/S1600536812003169. Epub 2012 Feb 4.

Abstract

In the title compound, C(30)H(25)NO(5)S, all the five-membered rings are in envelope conformations with the spiro and methylene C atoms as the flap atoms. Intra-molecular C-H⋯O inter-actions stabilize the mol-ecular structure and form S(6) and S(7) ring motifs. The mean plane through the hexa-hydro-pyrrolo-[1,2-c]thia-zole ring [r.m.s deviation of 0.0393 (1) Å] makes dihedral angles of 60.92 (5), 88.33 (4) and 84.12 (4)° with the terminal benzene ring and the mean planes of the mono and di-oxo substituted indan rings, respectively. Mol-ecules are linked by inter-molecular C-H⋯O inter-actions into a three-dimensional network. In addition, C-H⋯π and π-π inter-actions [centroid-to-centroid distance = 3.4084 (8) Å] further stabilize the crystal structure.