(Acetyl-acetonato-κO,O')bis-[2-(5-methyl-3-phenyl-pyrazin-2-yl-κN)phen-yl-κC]iridium(III)

Guo-Ping Ge; Chun-Yan Li; Cheng-Hao Gu; Mao-He Li; Xiao-Nan Xu

doi:10.1107/S1600536812006022

(Acetyl-acetonato-κO,O')bis-[2-(5-methyl-3-phenyl-pyrazin-2-yl-κN)phen-yl-κC]iridium(III)

Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):m306. doi: 10.1107/S1600536812006022. Epub 2012 Feb 17.

Authors

Guo-Ping Ge¹, Chun-Yan Li, Cheng-Hao Gu, Mao-He Li, Xiao-Nan Xu

Affiliation

¹ State Key Laboratory Base of Novel Functional Materials and Preparation Science, Institute of Solid Materials Chemistry, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, People's Republic of China.

Abstract

In the title complex, [Ir(C(17)H(13)N(2))(2)(C(5)H(7)O(2))], the Ir(III) atom is hexa-coordinated in a distorted octa-hedral geometry by two C,N-bidentate 2-(5-methyl-3-phenyl-pyrazin-2-yl)phenyl (mdpp) ligands and one O,O-bidentate acetyl-acetonate ligand. The dihedral angles between the phenyl rings and the pyrazine ring are 9.56 (14) and 58.99 (14)° for one mdpp ligand and 9.34 (14) and 79.94 (15)° for the other.