Bis[[aqua-(1H-imidazo[4,5-f][1,10]phenanthroline-κN,N)cadmium]bis-(μ-pyridine-2,3-dicarboxyl-ato)-κN,O:O;κO:N,O]

Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):m301. doi: 10.1107/S160053681200579X. Epub 2012 Feb 17.

Abstract

In the title compound, [Cd(2)(C(7)H(3)NO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(2)], the Cd(II) ion is six-coordinated by two N atoms from a 1H-imidazo[4,5-f][1,10]phenanthroline (IP) ligand, one N atom and one O atom from a pyridine-2,3-dicarboxyl-ate (pdc) ligand, one O atom from another pdc ligand and one water mol-ecule in a distorted octa-hedral geometry. Two Cd(II) ions are bridged by a pair of pdc ligands, forming a centrosymmetric dinuclear structure. Neighboring dinuclear units are linked by the coordinated water mol-ecules through O-H⋯N and O-H⋯O hydrogen bonds, forming a layer parallel to (011). The layers are further linked into a three-dimensional network through N-H⋯O hydrogen bonds. π-π inter-actions between the IP ligands further stabilize the supra-molecular structure [centroid-centroid distances = 3.579 (3), 3.686 (3), 3.710 (3), 3.766 (3) and 3.841 (3) Å].