Synthesis and characterization of 1,8-naphthalimide with [6]helicene skeleton

Org Biomol Chem. 2012 Apr 21;10(15):2934-6. doi: 10.1039/c2ob25223f. Epub 2012 Mar 12.

Abstract

A 1,8-naphthalimide with [6]helicene derivative scaffold has been designed and synthesized. The (P)- and (M)-enantiomers of the [6]helicene derivative were resolved by HPLC on a chiral column. The single crystal of the [6]helicene derivative exhibits an intermolecular interactions of the 1,8-naphthalimide units.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Chromatography, High Pressure Liquid
  • Crystallography, X-Ray
  • Cyclization
  • Light
  • Molecular Structure
  • Naphthalimides / chemical synthesis*
  • Photochemical Processes
  • Polycyclic Compounds / chemical synthesis*
  • Stereoisomerism

Substances

  • Naphthalimides
  • Polycyclic Compounds
  • helicenes