Photopolymerization inhibition dynamics for sub-diffraction direct laser writing lithography

Chemphyschem. 2012 Apr 23;13(6):1429-34. doi: 10.1002/cphc.201200006. Epub 2012 Mar 5.

Abstract

Selective inhibition of the polymerization leads to sub-diffraction feature sizes in direct writing lithography-a principle based on the idea of stimulated emission depletion (STED) microscopy. However, the detailed understanding of the inhibition process is a key point to further enhance the resolution of the system. The authors present experiments focused on the time dynamics of the inhibition process, clarifying possible photophysical pathways.