Revealing the conversion mechanism of CuO nanowires during lithiation-delithiation by in situ transmission electron microscopy

Chem Commun (Camb). 2012 May 18;48(40):4812-4. doi: 10.1039/c2cc30643c. Epub 2012 Mar 5.

Abstract

Being promising candidates for anodes in lithium-ion batteries (LIBs), transition metal oxide anodes utilizing the so-called conversion mechanism principle typically suffer from the severe capacity fading during the 1st cycle of lithiation-delithiation. Herein, we directly investigated these processes using an individual CuO nanowire anode and constructed a lithium ion battery (LIB) prototype within a transmission electron microscope.