Analysis of major congeners of polybromobiphenyls and polybromodiphenyl ethers in office dust using high resolution gas chromatography-mass spectrometry

Abstract

The study focused on analysis of polybromobiphenyls (PBBs) and polybromodiphenyl ethers (PBDEs) congeners in office dust obtained in Pretoria, South Africa. Of the 32 congeners considered for identification, (BB-1, 2, 4, 10, 15, 26, 29, 30, 31, 38, 49, 80, 103, 153, 155, 209 and BDE-3, 15, 17, 28, 47, 66, 77, 85, 99, 100, 126, 138, 153, 154, 183, 209) only BB-2, 4, 30, 153, 209 and BDE-47, 66, 85, 99, 153 and 209 congeners were detected. The sum of PBBs concentration detected in office dust ranged from <dl-196 ng g(-1) dry weight (dw) with a median and mean of 11.4 and 38.2 ng g(-1), respectively. On the other hand, the sum of PBDEs concentration detected ranged from 21.6 to 578.6 ng g(-1)dw with a median and mean of 162 and 169 ng g(-1)dw, respectively. A Spearman rank correlation between ∑(5)PBBs and ∑(6)PBDEs (r(s)=0.55, p=0.003), indicated a statistical significant positive correlation for the similarity of pollution sources for both compound classes. However, no correlation was observed between the number of electronic materials and summation of concentrations of PBBs and PBDEs congeners detected. Concentrations of PBDEs detected in this study are substantially lower than reported in office dust in developed countries.