SnCl2/TiCl3-mediated deoximation of oximes in an aqueous solvent

Molecules. 2012 Mar 1;17(3):2464-73. doi: 10.3390/molecules17032464.

Abstract

A simple procedure for SnCl(2)/TiCl(3)-mediated deoximation of ketoximes in an aqueous solvent is reported. Under the conditions developed in this effort, various ketones and aldehydes are produced in good to excellent yields.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acetophenones / chemistry
  • Catalysis
  • Hydrolysis
  • Oximes / chemistry*
  • Solvents / chemistry*
  • Tin Compounds / chemistry*
  • Titanium / chemistry*
  • Water / chemistry*

Substances

  • Acetophenones
  • Oximes
  • Solvents
  • Tin Compounds
  • Water
  • stannous chloride
  • Titanium
  • titanium trichloride
  • acetophenone