Abstract
The first report of a biocatalytic regioselective oxidative mono-cleavage of dialkenes was successfully achieved employing a cell-free enzyme preparation from Trametes hirsuta at the expense of molecular oxygen. Selected reactions were performed on a preparative scale affording high to excellent conversions and chemoselectivities.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Alkenes / chemical synthesis
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Alkenes / metabolism*
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Benzaldehydes / chemistry
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Benzaldehydes / metabolism*
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Biocatalysis
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Cell-Free System
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Oxidation-Reduction
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Oxygen / chemistry
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Stereoisomerism
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Substrate Specificity
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Trametes / enzymology*
Substances
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Alkenes
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Benzaldehydes
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Oxygen