3-Bromo-pyridin-2-amine

Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):o385. doi: 10.1107/S1600536811055541. Epub 2012 Jan 14.

Abstract

In the crystal structure of the title compound, C(5)H(5)BrN(2), mol-ecules assemble via pairs of N-H⋯N hydrogen bonds into inversion dimers using only the syn H atom on the amine group. These dimers then assemble further into two-dimensional layers via type I C-Br⋯Br [Br⋯Br = 3.693 (s6) Å] halogen bonding along the (102) plane.