Dual-functional click-triazole: a metal chelator and immobilization linker for the construction of a heterogeneous palladium catalyst and its application for the aerobic oxidation of alcohols

Chem Commun (Camb). 2012 Mar 21;48(24):2979-81. doi: 10.1039/c2cc18023e. Epub 2012 Feb 13.

Abstract

A novel SBA-15 supported catalyst PdL(n)@SBA-15 containing a 2-pyridyl-1,2,3-triazole ligand framework was prepared via a "click" route, in which the click-triazole acted as both a stable linker and a good chelator. The catalyst was characterized and applied for the aerobic oxidation of alcohols, and the product was obtained in up to 98% yield.