Electronic structure of ytterbium-implanted GaN at ambient and high pressure: experimental and crystal field studies

J Phys Condens Matter. 2012 Mar 7;24(9):095803. doi: 10.1088/0953-8984/24/9/095803. Epub 2012 Feb 9.

Abstract

The results of high-pressure low-temperature optical measurements in a diamond-anvil cell of bulk gallium nitride crystals implanted with ytterbium are reported in combination with crystal field calculations of the Yb(3+) energy levels. Crystal field analysis of splitting of the (2)F(7/2) and (2)F(5/2) states has been performed, with the aim of assigning all features of the experimental luminescence spectra. A thorough analysis of the pressure behavior of the Yb(3+) luminescence lines in GaN allowed the determination of the ambient-pressure positions and pressure dependence of the Yb(3+) energy levels in the trigonal crystal field as well as the pressure-induced changes of the spin-orbit coupling coefficient.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Crystallization
  • Electrons*
  • Gallium / chemistry*
  • Luminescence
  • Pressure
  • Temperature
  • Ytterbium / chemistry*

Substances

  • gallium nitride
  • Gallium
  • Ytterbium