Abstract
Carbene complexes of Ge(IV)- and Sn(IV)-fluorides have been synthesized by oxidative addition of 2,2-difluoro-1,3-dimethylimidazolidine and bis(dimethylamino)difluoromethane to GeCl(2)•dioxane and SnF(2). Chloride analogs of the Ge(IV) complexes were also isolated. All compounds were characterized in the solid state by single-crystal X-ray diffraction.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Chemical Phenomena
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Crystallography, X-Ray
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Fluorides / chemistry
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Germanium / chemistry
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Magnetic Resonance Spectroscopy
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Methane / analogs & derivatives*
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Methane / chemistry
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Molecular Structure
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Organometallic Compounds / chemical synthesis
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Organometallic Compounds / chemistry*
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Tin Compounds / chemical synthesis
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Tin Compounds / chemistry*
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X-Ray Diffraction
Substances
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Organometallic Compounds
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Tin Compounds
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Germanium
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carbene
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Methane
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Fluorides