Dibromido(2,9-dimethyl-1,10-phenanthroline-κN,N')cadmium

Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1846-7. doi: 10.1107/S1600536811050069. Epub 2011 Nov 30.

Abstract

In the title complex, [CdBr(2)(C(14)H(12)N(2))], the Cd(II) ion is tetra-coordinated by two N atoms of the bidentate 2,9-dimethyl-1,10-phenanthroline ligand and two bromide ions in a substanti-ally distorted CdN(2)Br(2) tetra-hedral geometry. In the crystal, inversion dimers linked by pairs of weak C-H⋯Br bonds generate R(2) (2)(14) loops. Aromatic π-π stacking [shortest centroid-centroid separation = 3.633 (2) Å] inter-actions occur within, and also link, the dimers into chains propagating parallel to [100].