trans-Bromido(pyrimidinyl-κC)bis-(triphenyl-phosphane-κP)palladium(II)

Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1820. doi: 10.1107/S1600536811049348. Epub 2011 Nov 25.

Abstract

In the title complex, [PdBr(C(4)H(3)N(2))(C(18)H(15)P)(2)], the geometry around the Pd atom is distorted square-planar with the Pd atom displaced by 0.0334 (14) Å from the BrP(2)C plane. The two Ph(3)P ligands are in trans positions, defining a P-Pd-P angle of 171.78 (5)°, while the pyrimidinyl and bromide ligands are trans to each other [C-Pd-Br = 174.63 (14)°].