[1,5-Bis(2-meth-oxy-phen-yl)thio-carbazo-nato-κN,S]phenyl-mercury(II)

Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1804. doi: 10.1107/S1600536811049099. Epub 2011 Nov 23.

Abstract

The title compound, [Hg(C(6)H(5))(C(15)H(15)N(4)O(2)S)], shows the metal-phenyl moiety coordinated out of plane with the thio-carbazo-nate ligand by 43.84 (6)°. Important geometrical parameters include Hg-S = 2.3653 (10) Å, Hg-C = 2.058 (4) Å and S-Hg-C = 179.06 (11)°. There is a weak coordination of an N atom of the ligand to Hg [Hg-N = 2.725 (3) Å]. S⋯Hg inter-actions[3.2928 (10) Å] form chains along [001], stabilizing the crystal structure.