Tetra-aqua-bis-{5-[4-(imidazol-1-yl-κN)phen-yl]tetra-zolido}manganese(II)

Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1757. doi: 10.1107/S1600536811047428. Epub 2011 Nov 12.

Abstract

In the title complex, [Mn(C(10)H(7)N(6))(2)(H(2)O)(4)], the Mn(2+) cation is located on a twofold rotation axis and is coordinated by two N atoms from two 5-[4-(imidazol-1-yl)phen-yl]tetra-zolide ligands and four O atoms from four water mol-ecules, displaying a distorted MnN(2)O(4) octa-hedral geometry. The crystal structure is stabilized by intermolecular O-H⋯N hydrogen bonds involving the coordinated water mol-ecules and the N atoms of the tetra-zolide group.