Tetra-aqua-bis-[3-(pyridin-4-yl)benzoato-κN]cobalt(II)

Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1743. doi: 10.1107/S1600536811046496. Epub 2011 Nov 12.

Abstract

In the title compound, [Co(C(12)H(8)NO(2))(2)(H(2)O)(4)], the Co atom lies on a twofold rotation axis and has an N(2)O(4) octa-hedral coordination environment formed by four O atoms of water mol-ecules in the equatorial plane and two apical N atoms of pyridine groups. An intricate three-dimensional supra-molecular network is formed by multiple O-H⋯O hydrogen bonds between the coordinated water mol-ecules and the uncoordinated carboxyl-ate groups.