Evaluation of spatial variability of soil arsenic adjacent to a disused cattle-dip site, using model-based geostatistics

Environ Sci Technol. 2011 Dec 15;45(24):10463-70. doi: 10.1021/es201726c. Epub 2011 Nov 29.

Abstract

This study investigated the spatial variability of total and phosphate-extractable arsenic (As) concentrations in soil adjacent to a cattle-dip site, employing a linear mixed model-based geostatistical approach. The soil samples in the study area (n = 102 in 8.1 m(2)) were taken at the nodes of a 0.30 × 0.35 m grid. The results showed that total As concentration (0-0.2 m depth) and phosphate-extractable As concentration (at depths of 0-0.2, 0.2-0.4, and 0.4-0.6 m) in soil adjacent to the dip varied greatly. Both total and phosphate-extractable soil As concentrations significantly (p = 0.004-0.048) increased toward the cattle-dip. Using the linear mixed model, we suggest that 5 samples are sufficient to assess a dip site for soil (As) contamination (95% confidence interval of ±475.9 mg kg(-1)), but 15 samples (95% confidence interval of ±212.3 mg kg(-1)) is desirable baseline when the ultimate goal is to evaluate the effects of phytoremediation. Such guidelines on sampling requirements are crucial for the assessment of As contamination levels at other cattle-dip sites, and to determine the effect of phytoremediation on soil As.

Publication types

  • Evaluation Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animal Husbandry / methods
  • Animals
  • Arsenic / analysis*
  • Cattle
  • Environmental Monitoring / methods*
  • Environmental Pollution / statistics & numerical data*
  • Models, Chemical*
  • Soil / chemistry*
  • Soil Pollutants / analysis*
  • Statistics as Topic

Substances

  • Soil
  • Soil Pollutants
  • Arsenic