N-[Amino-(azido)-meth-ylidene]-4-methyl-benzene-sulfonamide

Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o2140. doi: 10.1107/S1600536811026973. Epub 2011 Jul 23.

Abstract

In the title mol-ecule, C(8)H(10)N(5)O(2)S, the amino-(azido)-methyl and p-toluene-sulfonyl moieties are inclined almost at right angles with respect to each other, making a dihedral angle of 83.49 (6)°. An intra-molecular N-H⋯O hydrogen bond gives rise to the formation of six-membered ring with graph-set motif S(6). In the crystal, inter-molecular N-H⋯O hydrogen bonding is responsible for the formation of dimers about inversion centers, which are linked through another N-H⋯O inter-action along the b axis.