Tetra-μ(2)-acetato-diaqua-bis-(μ(2)-2-{[1,3-dihy-droxy-2-(oxidometh-yl)propan-2-yl]imino-meth-yl}phenolato)trimanganese(II,III) acetonitrile disolvate dihydrate

Yuhua Guo; Jianping Huang; Yong Huang; Junyue Wang; Youzhu Yu

doi:10.1107/S1600536811027899

Tetra-μ(2)-acetato-diaqua-bis-(μ(2)-2-{[1,3-dihy-droxy-2-(oxidometh-yl)propan-2-yl]imino-meth-yl}phenolato)trimanganese(II,III) acetonitrile disolvate dihydrate

Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1098. doi: 10.1107/S1600536811027899. Epub 2011 Jul 16.

Authors

Yuhua Guo¹, Jianping Huang, Yong Huang, Junyue Wang, Youzhu Yu

Affiliation

¹ Department of Chemistry and Environmental Engineering, Anyang Institute of Technology, Henan 455000, People's Republic of China.

Abstract

In the title complex, [Mn(II)Mn(III) (2)(C(11)H(13)NO(4))(2)(CH(3)CO(2))(4)(H(2)O)(2)]·2CH(3)CN·2H(2)O, there are two Mn(III) and one Mn(II) atoms. The Mn(II) atom lies on an inversion center and the Mn(III)-Mn(II)-Mn(III) angle is therefore 180°, as required by crystallographic symmetry. The Mn(III) and Mn(II) atoms are six-coordinated in a distorted octa-hedral geometry. In the crystal, complex mol-ecules and solvent mol-ecules are linked into a three-dimensional network by O-H⋯O and O-H⋯N hydrogen-bonding inter-actions.