New tetraester derivatives of 1,4,5,8-tetraazaanthracene have been prepared and characterized by spectroscopic and electrochemical techniques. The LUMO level of the compounds is close to -4 eV (the so-called air operating stability border in n-channel field effect transistors). Tetraesters were obtained with reasonable yields without the necessity of using high-quality reactants or solvents, resulting in their low cost.