Ti-STT: a new zeotype shape selective oxidation catalyst

Chem Commun (Camb). 2011 Nov 21;47(43):11867-9. doi: 10.1039/c1cc15175d. Epub 2011 Oct 5.

Abstract

A new zeotype titanium silicate oxidation catalyst with the STT topology has been synthesized from direct synthesis. Ti-STT has a microporous structure with small pore openings, allowing shape selective oxidation catalysis. The isomorphous substitution of Si by Ti in the framework has been confirmed by Raman, FT-IR, UV-VIS and XANES spectroscopies.