Amino acid based chiral N-amidothioureas. Acetate anion binding induced chirality transfer

Chem Commun (Camb). 2011 Nov 14;47(42):11784-6. doi: 10.1039/c1cc14995d. Epub 2011 Sep 30.

Abstract

N-Amidothioureas generated from amine-dimethylated natural L-phenylalanine and its D-enantiomer bearing a chiral carbon that is by 2 atoms or 3 chemical bonds away from the anion binding site establish chiral communication upon acetate anion binding to the thiourea moiety.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acetates / chemistry*
  • Amino Acids / chemistry*
  • Anions
  • Circular Dichroism
  • Magnetic Resonance Spectroscopy
  • Stereoisomerism
  • Thiourea / chemistry*

Substances

  • Acetates
  • Amino Acids
  • Anions
  • Thiourea