Luminescence on-off switching via reversible interconversion between inter- and intramolecular aurophilic interactions

Semi Han; Yu Young Yoon; Ok-Sang Jung; Young-A Lee

doi:10.1039/c1cc14351d

Luminescence on-off switching via reversible interconversion between inter- and intramolecular aurophilic interactions

Chem Commun (Camb). 2011 Oct 14;47(38):10689-91. doi: 10.1039/c1cc14351d. Epub 2011 Sep 5.

Authors

Semi Han¹, Yu Young Yoon, Ok-Sang Jung, Young-A Lee

Affiliation

¹ Department of Chemistry and Research Institute of Physics and Chemistry, Chonbuk National University, Jeonju 561-756, Korea.

PMID: 21892468
DOI: 10.1039/c1cc14351d

Abstract

Reversible interconversion between inter- and intramolecular AuAu interactions induces luminescence on/off switching in solid state. For the gold(I) photoluminescence system, intermolecular aurophilic interaction is a more significant factor than intramolecular aurophilic interaction.