Bis(μ-5-diisopropyl-amino-1,2,3,4-tetra-zolido-κN:N)bis-[(triisopropyl-phosphane)copper(I)]

Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m975-6. doi: 10.1107/S1600536811022719. Epub 2011 Jun 25.

Abstract

In the binuclear centrosymmetric crystal structure of the title compound, [Cu(2)(C(7)H(14)N(5))(2)(C(9)H(21)P)(2)], all atoms except those of the isopropyl groups are approximately co-planar. The Cu(II) atom is in a distorted trigonal-planar CuN(2)P coordination. Bond angles around the amino N atom suggest sp(2) hybridization. Several intra-molecular C-H⋯N inter-actions are present involving tetra-zolate N atoms.