1,1'-Di-tert-butyl-2,2',3,3',4,4',5,5'-octa-ethyl-1,1'-bis-tannole

Takuya Kuwabara; Masaichi Saito

doi:10.1107/S1600536811022951

1,1'-Di-tert-butyl-2,2',3,3',4,4',5,5'-octa-ethyl-1,1'-bis-tannole

Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m949. doi: 10.1107/S1600536811022951. Epub 2011 Jun 18.

Authors

Takuya Kuwabara¹, Masaichi Saito

Affiliation

¹ Department of Chemistry, Graduate School of Science and Engineering, Saitama University, Shimo-okubo, Saitama-city, Saitama 338-8570 Japan.

Abstract

The title compound, [Sn(2)(C(4)H(9))(2)(C(12)H(20))(2)], has two 1-stannacyclo-penta-diene skeletons related by inversion symmetry located at the mid-point of the Sn-Sn bond [2.7682 (2) Å]. Thus, the asymmetric unit comprises one half-mol-ecule. The planarity of the stannacyclo-penta-diene ring is illustrated by the dihedral angle of 0.3 (1)°, defined by the C(4) and C-Sn-C planes. To avoid steric repulsion, the two stannole rings are oriented in an anti fashion through the Sn-Sn bond. These structural features are similar to those of other bis-tannoles.