Bis[4-bromo-2-(ethyl-imino-meth-yl)phenolato-κN,O]nickel(II)

Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m858. doi: 10.1107/S1600536811020885. Epub 2011 Jun 4.

Abstract

In the title complex, [Ni(C(9)H(9)BrNO)(2)], the Ni(II) ion lies on an inversion centre and is coordinated in a slightly distorted square-planar geometry by two N atoms and two O atoms from two symmetry-related bidentate 4-bromo-2-(ethyl-imino-meth-yl)phenolate ligands. The complex forms a one-dimensional chain in the crystal structure through short C-H⋯Br contacts (H⋯Br = 3.009 Å).