Synthesis of new metalloporphyrin triads: efficient and versatile tripod optical sensor for the detection of amines

Sara M A Pinto; Mirtha A O Lourenço; Mário J F Calvete; Artur R Abreu; Mário T S Rosado; Hugh D Burrows; Mariette M Pereira

doi:10.1021/ic200727f

Synthesis of new metalloporphyrin triads: efficient and versatile tripod optical sensor for the detection of amines

Inorg Chem. 2011 Sep 5;50(17):7916-8. doi: 10.1021/ic200727f. Epub 2011 Aug 5.

Authors

Sara M A Pinto¹, Mirtha A O Lourenço, Mário J F Calvete, Artur R Abreu, Mário T S Rosado, Hugh D Burrows, Mariette M Pereira

Affiliation

¹ Departamento de Química, Universidade de Coimbra, Coimbra, Portugal.

PMID: 21819057
DOI: 10.1021/ic200727f

Abstract

Zinc and manganese complexes of porphyrin triads have been synthesized and are shown to be efficient as highly sensitive and selective tripod optical sensors for amines at the picomolar level.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Amines / analysis*
Chemistry Techniques, Synthetic
Magnetic Resonance Spectroscopy
Manganese / chemistry
Metalloporphyrins / chemical synthesis*
Metalloporphyrins / chemistry*
Models, Molecular
Molecular Structure
Optical Devices*
Spectrophotometry, Ultraviolet
Zinc / chemistry

Substances

Amines
Metalloporphyrins
Manganese
Zinc