1-(2-Alkynylphenyl)ketoximes react with Lawesson's reagent catalyzed by InCl(3) and cyanuric chloride leading to 4-methylene-4H-benzo[d][1,3]thiazines in good yields. This tandem reaction proceeds with high efficiency through Beckmann rearrangement, thioamide formation, and intramolecular nucleophilic cyclization.
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