Sequential functionalization of porous coordination polymer crystals

Angew Chem Int Ed Engl. 2011 Aug 22;50(35):8057-61. doi: 10.1002/anie.201101924. Epub 2011 Jul 14.

Abstract

Crystal extractor: heterostructured porous coordination polymer crystals fabricated using epitaxial growth have two contradictory porous functions, namely size selectivity and high storage. The crystals not only extract linear petroleum molecules from a mixture with its branched isomer, even at very low concentrations of linear isomer (1 wt %), but also shows improved accumulation of the molecules in its pores.