Bis[4-(2-hy-droxy-benzyl-idene-amino)-benzoato-κO]tetra-kis-(methanol-κO)cadmium

Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m685-6. doi: 10.1107/S1600536811015364. Epub 2011 May 7.

Abstract

In the title mononuclear complex, [Cd(C(14)H(10)NO(3))(2)(CH(3)OH)(4)], the Cd(2+) cation is situated on an inversion centre. It exhibits a distorted octa-hedral coordination, defined by two carboxyl-ate O atoms from two monodentate anions and by four O atoms from four methanol mol-ecules. The crystal structure comprises intra-molecular O-H⋯O and O-H⋯N, and inter-molecular O-H⋯O hydrogen bonds. The latter help to construct a layered structure extending parallel to (100).