3-Chloro-pyridin-2-amine

Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):o1138. doi: 10.1107/S1600536811013432. Epub 2011 Apr 16.

Abstract

In the title compound, C(5)H(5)ClN(2), a by-product in the synthesis of ethyl 2-(3-chloro-pyridin-2-yl)-5-oxopyrazolidine-3-carboxyl-ate, the amine groups form inter-molecular hydrogen-bonding associations with pyridine N-atom acceptors, giving centrosymmetric cyclic dimers. Short inter-molecular Cl⋯Cl inter-actions [3.278 (3) Å] also occur.